Complexes of 2-Thioracil with Some Divalent Metal Ions
Bardi N. Singh, Udai P. Singh, R. Ghose and Animesh K. Ghose*

Department of Chemistry, Faculty of Science, Banaras Hindu University, Varansi-221 005, India  

Abstract

Simple complexes of Mn(II), Co(II), Ni(II), Cu(II), Zn(II) and Cd(II) with 2-thiouracil (TU) have been prepared and characterized by various physico-chemical methods. IR results show that 2-thiouracil is bidentate in all cases, coordinating through sulphur and one nitrogen atom. The X-ray powder pattern of the complexes suggests orthorhombic symmetry for Mn(II)-2TU, Co(II)-2TU, Mi(II)-2TU, Zn(II)-2TU and tetragonal symmetry for Cu(II)-2TU complexes.

Keywords

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  • Asian J. Chem. /
  •  1993 /
  •  5(2) /
  •  pp 262-265