Triphenyltelluronium Haloplumbates (II)
K.K. Verma*, Anita Saini and O.P. Agrawal
 Department of Chemistry, M.D.University, Rohtak-124 001, India
Abstract

The paper describes the synthesis and properties of Triphenyltelluronium haloplumbates (II). [(Ph3Te)+]2[PbCI4]2–, [Ph3Te]+[PbBr3]– and [Ph3Te]+[PbI3]– type products are obtained by reactions of Ph3TeX with PbX2 in presence of HX (X ═ Cl, Br, I respectively). Conductivity, molecular weight determinations and 1H nmr data are consistent with their dissociation in dilute solution as Ph3Te+ and PbCl42– or Ph3Te+ and PbBr3- or PbI3 units. The absence of Te–Pb and Te–X vibrations in the far i. r. spectra of these compounds also supports their formulation as ionic compounds.

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  • Asian J. Chem. /
  •  1991 /
  •  3(4) /
  •  pp 379-384