Synthesis and Characterization of Some New Organo Antimony Xanthates

B.K. Dwivedi*, H.N. Mehrotra and Damini Mehrotra

Department of Chemistry, B.S.N.V. Degree College Lucknow-226 001, India

Abstract

Triphenyl stibine dibromide was allowed to react with potassium alkyl or aryl xanthates, which yielded organo antimony xanthates of general formulae Ph3Sb (S2COR)2, (where R &9552; methyl, ethyl, propyl, isopropyl, butyl, isobutyl, amyl and benzoyl), which, were characterized, through elemental analysis, molecular weight, conductance, T.G.A. and IR spectral data. Infrared spectral data clearly indicates that the xanthate ligand is bonded to organo antimony moiety through the sulphur and not through oxygen molecule.

Keywords

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  • Asian J. Chem. /
  •  1991 /
  •  3(1) /
  •  pp 58-62