Synthesis and Characterization of Some New [RR′SeL] Complexes (L = Macrocyclic Ligand): A Photoelectron Spectroscopic Study (Part-II)

Uday Singh Patel*, Ranjeet Singh Chauhan, Sandeep Singh, Ramakant, Ashish Rajak and Shekhar Srivastava*

Department of Chemistry, University of Allahabad, Prayagraj-211002, India

*Corresponding authors: E-mail: uday.auchem16@gmail.com; shekhsri@rediffmail.com

Abstract

Forty eight complexes of type [RR′SeL] (where R = R′ = CH3; R = R′ = n-C4H9; R = R′ = n-C8H17; R = R′ = i-C3H7; R = R′ = C6H5; R = C6H5, R′ = C2H5; R = C6H5, R′ = CH3 and R = C6H5, R′ = CH2Cl; L = newly prepared macrocyclic ligands) have been synthesized and characterized by elemental analysis, molar conductivity, IR and XPS data. An octahedral geometry was established for all these prepared complexes.

Keywords

Selenium, Macrocyclic ligand, X-ray photoelectron spectroscopy.

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