Bed Height of Zeolite Affected CO2 Hydrate Formation Using High Pressure Volumetric Analyzer

A.H. Mohd Hafiz1,*, C.E. Snape2 and Lee Stevens2

1Faculty of Science and Technology, Islamic Science University of Malaysia (USIM), 71800 Nilai, Negeri Sembilan, Malaysia

2Cleaner Fossil Energy and Carbon Capture Technologies Research Group, Faculty of Engineering, The University of Nottingham, Nottingham NG7 2RD, U.K.

*Corresponding author: Fax: +60 6 7986566; Tel: + 60 11 11069430; E-mail: mhafiz.a.h@usim.edu.my

Abstract

The formation of CO2 hydrate in this work was experimentally investigated using a high pressure volumetric analyzer (HPVA). The investigations in pure CO2 gas systems (at 275 K and 36 bar) highlighted the effect of bed height on CO2 hydrate formation by employing standard silica gel and zeolite 13X as porous mediums. The CO2 uptake of zeolite 13X saturated with 5.6 mol % tetrahydrofuran and 0.01 mol % sodium dodecyl sulfate (zeolite 13X-5) increased from 0 to 0.58 mmol of CO2 per g of H2O when the bed height was reduced from 3 to 2 cm.

Keywords

Greenhouse effect, CO2 hydrate, Driving force, Bed height, Carbon capture and storage.

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