Spectral Studies of N-Benzoylglycine hydrazide, Acetone (N-benzoyl)glycyl hydrazone and their Ce(III) and Y(III) Complexes

Thatavarthi R. Rao* and Genda Singh

Department of Chemistry, Faculty of Science Banaras Hindu University, Varanasi-221 005, India

Abstract

N-Benzoylglycine hydrazide (BzGH) and acetone (N-benzoyl) glycyl hydrazone (BzAGH) have been synthesized, characterized by IR, 1H and 13C NMR and mass spectral studies and their complexes of the types M(BzGH)2Cl3·nH2O and M(BzAGH)Cl3·3H2O where M ═ Ce(III) and Y(III) have been synthesized and characterized by analytical data, molar conductance, magnetic susceptibility, IR, 1H and 13C NMR spectral techniques. Infrared and 1H NMR spectra suggest that both the ligands act as neutral bidentate species in their complexes.

Keywords

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  • Asian J. Chem. /
  •  1990 /
  •  2(2) /
  •  pp 111-118