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A Novel Pyridazinium Ionic Liquid: Ultrasound Synthesis, Characterization and its Analytical Application Using Cyclic Voltammetry and High Performance Liquid Chromatography

Ali F. Alghamdi* and M. Messali

Department of Chemistry, Faculty of science, Taibah University, Al-Madina Al-Mounawara 30002, Saudi Arabia

*Corresponding author: Tel: +966 48460008; E-mail: alifh2006@hotmail.com
Abstract

Synthesis of 1-(3-phenylpropyl)pyridazin-1-ium bromide (2), a novel ionic liquid (IL), was achieved using an efficient, green ultrasound-assisted process. The structure was characterized by FT-IR, 1H NMR, 13C NMR and mass spectrometry. The cyclic voltammetric behaviour of this new ionic liquid 2 (5 × 10-5 mol L-1 and 50 mV/s scan rate) was investigated in Britton-Robinson (B-R), acetate and phosphate buffers at pH 3. A broad cathodic cyclic voltammetric peak at E1/2 = -780 mV was recorded using hanging mercury drop, glassy carbon and graphite electrodes vs. Ag/AgCl reference electrode. Electrochemical reduction of the analyte was irreversible and diffusion-controlled. High performance liquid chromatography (HPLC) of 2 was investigated using a C-18 (5 μm) column for separation from interferences. A mobile phase containing methanol:acetonitrile:phosphate buffer at pH 3 (30:30:40 v/v/v %) was used and elution of 2 was monitored with UV detection at 254 nm. The retention time of this compound was recorded to be 2.152 min.
Keywords

Green procedure, Ionic liquids, Cyclic voltammetry, B-R buffer, HPLC, Mobile phase.
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