Effect of Tertiary Amines on the Hydrolysis Kinetics of Benzoyl Chloride in Water-Dioxane Solutions

Mohammad A. Batiha1,*, Elena A. Chizhova2 and Marwan M. Batiha1

1Faculty of Engineering, Al-Hussein Bin Talal University, 71111 Ma'an, Jordan

2Ivanovo State University of Chemistry and Technology, 153000 Ivanovo, Russia

*Corresponding author: E-mail: mbatiha@ahu.edu.jo

Abstract

The main object of this study was to study the effect of pyridine, 2-methyl pyridine, 3-methyl pyridine, 2,6-dimethyl pyridine, quinoline and tribenzylamine on the hydrolysis kinetics of benzoyl chloride in water-dioxane solutions. The investigation has been made by means of gas-liquid chromatography measurements. Almost equal rate constants have been determined for the hydrolysis reaction of benzoyl chloride in dioxane solutions. The catalytic effect of the studied range of tertiary amines on the hydrolysis reaction of benzoyl chloride was determined.

Keywords

Benzoyl chloride, Hydrolysis kinetics, Tertiary amines, Water-dioxane solutions.

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