| Synthesis and Crystal Structure of a New 2D-Supramolecular Complex: [Cd(C17H13N2O2)2(C2H6O)2] |
Yin-Xia Sun*, Rui-e Lu, Qing-Ying Lan, Xiao-Yan Zhang and Fei-Xia Ma |
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China
*Corresponding author: E-mail: sun_yinxia@163.com |
| Abstract
The molecule of the cadmium(II) complex i.e., bis(l-phenyl-3-methyl-4-benzoyl-5-pyrazolone)-bis(ethanol)cadmium(II), [Cd(C17H13N2O2)2(C2H6O)2], is rigorously centrosymmetric [symmetry codes: -x, -y, -z]. The Cd(II) center exhibits a slightly distorted octahedral geometry with two ligand units forming the basal O2O2 coordination plane and two other oxygen atoms from two coordinated ethanol molecules in the axial position. In the crystal structure, intermolecular O-H···N hydrogen bonds and C-H···p stacking interactions link the complex molecules into infinite 2D supramolecular structure. |
| Keywords
Cadmium(II) complex, l-Phenyl-3-methyl-4-benzoyl-5-pyrazolone, Supramolecular structure. |
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