| Synthesis, Characterization and Electrochemical Study of Transition Metals [Cu(II), Fe(III)] Complexes of Fumarate 2,9-Dimethyl-1,10-phenanthroline |
| QINGZHU CHU, MEILING ZHANG and CAIFENG DING* |
College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao-266042, Shandong, P.R. China Tel/Fax: (86)(532)84022750; E-mail: dingcaifeng2003@163.com; baochai76@yahoo.com.cn |
| Abstract
Two new complexes containing 2,9-dimethyl-1,10-phenanthroline (phen), fumarate and transition metals, Cu2(phen)2(fumarate)(H2O)2]Cl2 (1), [Fe2(phen)2(fumarate)(H2O)2](NO3)4 (2), were synthesized and characterized. The crystal structure of compound 1 was determined by X-ray crystallography. The thermal decomposition was studied by thermal analysis TG-DTG. The interaction of these complexes with DNA was studied by cyclic voltammetry (CV) and differential pulse voltammetry (DPV). The electrochemical experimental results indicate that these complexes could interact with DNA. |
| Keywords
Complexes, Crystal structure, Thermal analysis, Electrochemical study, DNA. |
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