| Synthesis and Structural Studies on Mn(II) Complexes with Some β-ketoimines. |
| S. K. AGARWAL * and MUKESH KUMAR SUBHASH CHAND. |
S. K. AGARWAL * and MUKESH KUMAR
Chemistry Department
Lajpat Rai (P.G.) College
Sahibabad-201 005, India
and
SUBHASH CHAND
Chemistry Department
Marathwada Institute of Technology, Aurangabad-431 005, India. |
| Abstract
Mn(II) complexes having the formulae Mn(L)2, where L ═ 4-p-dimethyl
amino-anilino-3-penten-2-one, 4-(β-mercapto) ethyl amino-3-penten-2-one,
4-(4-phenyl thiazole-2) amino-3-penten-2-one, 4-(2-hydroxy-penten)-
3-pyridyl ketoimine and O-(4-imino-3-penten-2-one) benzene sulphonic
acid have been prepared. The complexes show non-electrolytic
behaviour. All the complexes have either octahedral or high spin tetrahedral
geometries. |
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