Neutral Three-coordinate Complexes of Mercury(II) Invohing Coordinated Cyano Groups

I. S. AHUJA * AND SHAILENDRA TRIPATHI C. L. YADAVA

I. S. AHUJA * AND SHAILENDRA TRIPATHI
Chemistry Department
Banaras Hindu University
Varanasi-221 005, India
and
C. L. YADAVA
Chemistry Department
Komia Nehru Institute of Physical and Social Sciences
Sultanpur-228118, India

Abstract

1 : 1 Complexes of mercury(II) cyanide with 2-benzylpyridine, 4-picolylamine,
2-benzoylpyridine, 4-benzoylpyridine, 1,3-bis-(4-pyridyl) propane,
quinoline, 6-methylquinoline; benzo(f)quinoline, isoquinoline,
3-methylisoquinoline, nicotinamide and N-methylnicotinamide have
been synthesized. Molar conductances, molecular weight determinations
and infrared spectral measurements down to 200 cm–1 show that all
these compounds are neutral species having monomeric three-coordinated
environments around mercury(II) in the solid state.

Keywords

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  • Asian J. Chem. /
  •  1989 /
  •  1(4) /
  •  pp 384-391