A Kinetic Study of Oxidation of Aliphatic Ketone with N-Bromobenzamide in Acidic Medium

R. P. Dubey, Geeta Kumari and S. K. Solanki*
School of Studies in Chemistry, Vikram University, Ujjain-456 010, India
Abstract

The kinetics of oxidation of ethyl methyl ketone by N-bromobenzamide (NBB) in aquoacetic acid media has been done. The reaction has a zero order dependency on [NBB] and a first order dependency with respect to substrate [ethyl methyl ketone]. The reaction is catalysing by H+. The effect of ionic strength, mercuric acetate and product [benzamide] variations has been studied. Various thermodynamic parameters have been computed and a probable reaction mechanism consistent with the kinetic results has been suggested.

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  • Asian J. Chem. /
  •  1989 /
  •  1(3) /
  •  pp 249-253